In₄Bi₂S₉ is a quaternary chalcogenide ceramic compound belonging to the indium bismuth sulfide family, characterized by mixed-valence metal cations and sulfide anions in a layered crystal structure. This material is primarily of research and developmental interest for optoelectronic and thermoelectric applications, where its narrow bandgap and layered architecture offer potential advantages in light absorption, charge transport, and phonon scattering compared to binary or ternary sulfides. It represents an emerging class of multinary sulfide ceramics being explored for next-generation energy conversion and photovoltaic technologies.
Compliance & Regulations
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 0.1934 | lb/in³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg) | 1.620 | eV | DFT · OptB88vdW | ||
High-Frequency Dielectric Constant (ε∞)(ε∞) | 10.34 | - | DFT · OptB88vdW | ||
Electron Effective Mass(m*e) | 1.850 | me | DFT · OptB88vdW · 27°C | ||
Hole Effective Mass(m*h) | 2.893 | me | DFT · OptB88vdW · 27°C | ||
Magnetic Moment(μB) | 0.000 | µB | DFT · OptB88vdW | ||
Thermoelectric Power Factor(PF)2 entries | 0.000900 | W/(m·K²) | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 0.000572 | W/(m·K²) | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Seebeck Coefficient(S)2 entries | -158.1 | μV/K | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 325.8 | μV/K | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.000 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf) | -0.5608 | eV/atom | DFT · OptB88vdW |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data