ZnGeP₂ is a II-IV-V₂ compound semiconductor with a direct bandgap, belonging to the chalcopyrite crystal family. It is primarily used in nonlinear optical and infrared photonic applications, where its combination of wide transparency window and strong nonlinear optical coefficients makes it valuable for frequency conversion and mid-infrared laser systems. The material is notably harder and more chemically stable than alternative infrared crystals like CdGeAs₂, making it preferred for demanding optical environments, though it remains more specialized and less mature than conventional semiconductors like GaAs.
Compliance & Regulations
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Bulk Modulus(K)2 entries | 10,866.7 | ksi | DFT | ||
| ↳ | 10,731.3 | ksi | DFT · OptB88vdW | ||
Poisson's Ratio(ν) | 0.2300 | - | DFT · OptB88vdW | ||
Shear Modulus(G)2 entries | 7,095.3 | ksi | DFT | ||
| ↳ | 7,253.3 | ksi | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 0.1456 | lb/in³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg)3 entries | 2.340 | eV | Measured | ||
| ↳ | 1.054 | eV | DFT · OptB88vdW | ||
| ↳ | 1.932 | eV | DFT · TBmBJ | ||
Dielectric Constant (Relative Permittivity)(εr)2 entries | 15.29 | - | DFT · OptB88vdW | ||
| ↳ | 13.39 range 12.61–14.17median of 2 measurements | - | DFT · PBEsol | ||
High-Frequency Dielectric Constant (ε∞)(ε∞)2 entries | 13.49 | - | DFT · OptB88vdW | ||
| ↳ | 9.046 | - | DFT · TBmBJ | ||
Electron Effective Mass(m*e) | 0.2567 | me | DFT · OptB88vdW · 27°C | ||
Hole Effective Mass(m*h) | 0.5833 | me | DFT · OptB88vdW · 27°C | ||
Magnetic Moment(μB) | 0.000 | µB | DFT · OptB88vdW | ||
Piezoelectric Modulus(eij)2 entries | 0.6880 | C/m² | DFT · OptB88vdW | ||
| ↳ | 0.05073 | C/m² | DFT · PBE | ||
Piezoelectric Stress Tensor(eij) | Matrix (redacted) | C/m² | DFT · PBE | ||
Thermoelectric Power Factor(PF)2 entries | 0.00419 | W/(m·K²) | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 0.00273 | W/(m·K²) | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Seebeck Coefficient(S)2 entries | -210.8 | μV/K | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 241 | μV/K | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Spectroscopic Limited Maximum Efficiency (SLME)(SLME) | 24.45 | % | DFT · TBmBJ |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.000 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf) | -0.2317 | eV/atom | DFT · OptB88vdW |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data