Thulium fluoride (TmF₃) is a rare-earth fluoride ceramic belonging to the lanthanide fluoride family, characterized by high density and significant stiffness. This material is primarily investigated in optical and photonic applications, where rare-earth fluorides serve as host matrices for laser gain media and infrared transparent windows; TmF₃ specifically is notable in solid-state laser systems and mid-infrared optical components where its fluoride chemistry provides superior transparency in wavelength ranges where oxide ceramics fall short. Engineers select rare-earth fluorides like TmF₃ when applications demand low phonon energy, chemical inertness in corrosive environments, or specific luminescent properties that cannot be achieved with conventional oxides or glasses.
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| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Bulk Modulus(K) | 23,726.7 | ksi | DFT · OptB88vdW | ||
Poisson's Ratio(ν) | 0.3500 | - | DFT · OptB88vdW | ||
Shear Modulus(G) | 8,654.4 | ksi | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 0.3324 | lb/in³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg)2 entries | 5.813 | eV | DFT · OptB88vdW | ||
| ↳ | 7.239 | eV | DFT · TBmBJ | ||
Dielectric Constant (Relative Permittivity)(εr) | 44.08 | - | DFT · OptB88vdW | ||
High-Frequency Dielectric Constant (ε∞)(ε∞)2 entries | 3.105 | - | DFT · OptB88vdW | ||
| ↳ | 2.561 | - | DFT · TBmBJ | ||
Magnetic Moment(μB) | 0.000 | µB | DFT · OptB88vdW | ||
Piezoelectric Modulus(eij) | 0.000 | C/m² | DFT · OptB88vdW | ||
Thermoelectric Power Factor(PF)2 entries | 0.000969 | W/(m·K²) | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 0.000673 | W/(m·K²) | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Seebeck Coefficient(S)2 entries | -147.2 | μV/K | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 552.4 | μV/K | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Spectroscopic Limited Maximum Efficiency (SLME)(SLME) | 0.000 | % | DFT · TBmBJ |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.02140 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf)2 entries | -4.050 | eV/atom | DFT · OptB88vdW | ||
| ↳ | -4.391 | eV/atom | Measured |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data