Sm₂Zr₂O₇ is a rare-earth zirconate ceramic compound belonging to the pyrochlore oxide family, composed of samarium and zirconium oxides. This material is primarily of research and developmental interest for thermal barrier coating (TBC) applications in advanced aerospace and power generation, where it offers potential advantages over conventional yttria-stabilized zirconia (YSZ) due to its lower thermal conductivity and improved phase stability at ultra-high temperatures. The samarium-zirconate system represents an emerging alternative in the thermal protection material space, particularly for next-generation gas turbines and hypersonic vehicle applications where incremental improvements in thermal performance and durability translate to significant engineering gains.
Compliance & Regulations
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 0.2356 | lb/in³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg)2 entries | 3.302 | eV | DFT · OptB88vdW | ||
| ↳ | 4.443 | eV | DFT · TBmBJ | ||
High-Frequency Dielectric Constant (ε∞)(ε∞) | 1.617 | - | DFT · TBmBJ | ||
Electron Effective Mass(m*e) | 0.8500 | me | DFT · OptB88vdW · 27°C | ||
Hole Effective Mass(m*h) | 1.500 | me | DFT · OptB88vdW · 27°C | ||
Magnetic Moment(μB) | 0.000 | µB | DFT · OptB88vdW | ||
Thermoelectric Power Factor(PF)2 entries | 0.000863 | W/(m·K²) | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 0.00162 | W/(m·K²) | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Seebeck Coefficient(S)2 entries | -178.5 | μV/K | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 380.1 | μV/K | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Spectroscopic Limited Maximum Efficiency (SLME)(SLME) | 0.000 | % | DFT · TBmBJ |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.000 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf) | -3.726 | eV/atom | DFT · OptB88vdW |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data