Sodium azide (NaN₃) is an inorganic ceramic compound primarily known as an energetic material and chemical reagent rather than a structural ceramic. It is used industrially as the active component in automotive airbag inflators, where rapid decomposition generates nitrogen gas for rapid inflation, and in specialized applications requiring controlled explosive or propellant behavior. Engineers select NaN₃-based systems for safety-critical applications where reliable, fast gas generation is essential, though its toxic decomposition byproducts and handling hazards require careful system design and containment.
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| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Bulk Modulus(K) | 32.62 | GPa | DFT · OptB88vdW | ||
Poisson's Ratio(ν) | 0.3700 | - | DFT · OptB88vdW | ||
Shear Modulus(G) | 14.25 | GPa | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 1.930 | kg/m³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg)2 entries | 4.040 | eV | DFT · OptB88vdW | ||
| ↳ | 5.284 | eV | DFT · TBmBJ | ||
Dielectric Constant (Relative Permittivity)(εr)2 entries | 6.707 | - | DFT · OptB88vdW | ||
| ↳ | 5.160 | - | DFT · PBE | ||
High-Frequency Dielectric Constant (ε∞)(ε∞)2 entries | 3.414 | - | DFT · OptB88vdW | ||
| ↳ | 2.854 | - | DFT · TBmBJ | ||
Electronic Dielectric Tensor(ε∞) | Matrix (redacted) | - | DFT · PBE | ||
Total Dielectric Tensor(ε) | Matrix (redacted) | - | DFT · PBE | ||
Magnetic Moment(μB) | 0.000 | µB | DFT · OptB88vdW | ||
Piezoelectric Modulus(eij) | 0.000 | C/m² | DFT · OptB88vdW | ||
Thermoelectric Power Factor(PF)2 entries | 0.00185 | W/(m·K²) | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 0.000994 | W/(m·K²) | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Seebeck Coefficient(S)2 entries | -256.8 | μV/K | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 422.4 | μV/K | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Spectroscopic Limited Maximum Efficiency (SLME)(SLME) | 0.000 | % | DFT · TBmBJ |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.00300 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf) | -0.1485 | eV/atom | DFT · OptB88vdW |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data