Lithium yttrium fluoride (LiYF₄) is a crystalline ceramic compound combining lithium, yttrium, and fluoride ions, primarily investigated as a host material for rare-earth dopants in photonic and laser applications. This material is notable for its optical transparency in the ultraviolet and infrared regions, making it valuable for solid-state laser systems, particularly when doped with rare-earth ions like erbium or neodymium for fiber lasers and amplifiers used in telecommunications and industrial processing. Engineers select LiYF₄ over alternative fluoride ceramics for its favorable thermal stability, low phonon energy (enabling efficient energy transfer between dopant ions), and compatibility with fiber coupling in compact laser modules.
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| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Bulk Modulus(K) | 12,525.5 | ksi | DFT · OptB88vdW | ||
Poisson's Ratio(ν) | 0.3300 | - | DFT · OptB88vdW | ||
Shear Modulus(G) | 5,205.4 | ksi | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 0.1424 | lb/in³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg) | 8.150 | eV | DFT · OptB88vdW | ||
Dielectric Constant (Relative Permittivity)(εr)2 entries | 8.060 | - | DFT · OptB88vdW | ||
| ↳ | 5.275 range 2.361–8.189median of 2 measurements | - | DFT · PBEsol | ||
High-Frequency Dielectric Constant (ε∞)(ε∞) | 2.367 | - | DFT · OptB88vdW | ||
Magnetic Moment(μB) | 0.000 | µB | DFT · OptB88vdW | ||
Piezoelectric Modulus(eij) | 0.000 | C/m² | DFT · OptB88vdW | ||
Spectroscopic Limited Maximum Efficiency (SLME)(SLME) | 1.290 | % | DFT · TBmBJ |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.000 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf) | -3.977 | eV/atom | DFT · OptB88vdW |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data