LiF

ceramic
· LiF

Lithium fluoride (LiF) is an inorganic ceramic compound that forms a cubic crystalline structure with high ionic bonding. It is primarily used in optical and thermal applications where transparency, chemical inertness, and thermal stability are critical, particularly in infrared spectroscopy windows, laser optics, and specialized detector systems. LiF is chosen over alternative optical ceramics when broadband IR transmission, high UV resistance, and extreme chemical durability are required, though its hygroscopic nature and higher cost limit its use to applications where these performance advantages justify the premium.

infrared optics and windowslaser systems and opticsspectroscopy instrumentationthermal and radiation detectionsemiconductor processingnuclear and particle physics detectors

Compliance & Regulations

?Conflict Free?RoHS?REACH?TSCA?Prop 65
PropertyValueUnitConditionsSource
Bulk Modulus(K)3 entries
69.88
GPa
69.88
GPa
73.93
GPa
Elastic Compliance Tensor(Sij)
Matrix (redacted)
1/GPa
Elastic Anisotropy(AU)
0.1587
-
Elastic Stiffness Tensor(Cij)
Matrix (redacted)
Pa
Poisson's Ratio(ν)2 entries
0.2068
-
0.2100
-
Shear Modulus(G)3 entries
50.94
GPa
50.94
GPa
55.28
GPa
N entriesMultiple entries per property — large groups are collapsed; click a summary row to expand. Use filters above to narrow by form / heat treatment / basis.
Verified Unverified Low confidence (<80%) Link to source
PropertyValueUnitConditionsSource
Density(ρ)
2.662
kg/m³
Verified Unverified Low confidence (<80%) Link to source
PropertyValueUnitConditionsSource
Band Gap(Eg)2 entries
11.70
eV
9.479
eV
Dielectric Constant (Relative Permittivity)(εr)2 entries
8.817
-
5.697
range 2.083–9.311median of 2 measurements
-
Magnetic Moment(μB)
0.000
µB
Piezoelectric Modulus(eij)
0.000
C/m²
Seebeck Coefficient(S)
-189.6
µV/K
N entriesMultiple entries per property — large groups are collapsed; click a summary row to expand. Use filters above to narrow by form / heat treatment / basis.
Verified Unverified Low confidence (<80%) Link to source
PropertyValueUnitConditionsSource
Energy Above Hull(ΔEhull)
0.03590
eV/atom
Formation Energy(ΔHf)2 entries
-3.197
eV/atom
-3.155
eV/atom
N entriesMultiple entries per property — large groups are collapsed; click a summary row to expand. Use filters above to narrow by form / heat treatment / basis.
Verified Unverified Low confidence (<80%) Link to source

Regulatory Screening

Environmental

RoHS, REACH, and Prop 65 statuses are validated against official substance lists (ECHA SVHC Candidate List, OEHHA Prop 65, RoHS Annex II). Other regulations are estimated from composition and material classification. All screening is a starting point for due diligence — always verify with your supplier before making compliance decisions.