Li4MnNi3P4O16 is a lithium-based ceramic compound containing manganese, nickel, and phosphate phases, belonging to the family of polyanion-framework ceramics under active research for energy storage applications. This material is primarily investigated as a cathode or electrolyte component in advanced lithium-ion battery systems, where its mixed-metal composition and phosphate structure offer potential advantages in ionic conductivity, thermal stability, and cycle life compared to conventional oxide cathodes. As a research-stage compound rather than a commercial product, it represents the broader push toward high-energy-density and long-life battery chemistries for electric vehicles and grid storage.
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| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 0.1354 | lb/in³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg) | 0.2540 | eV | DFT · OptB88vdW | ||
High-Frequency Dielectric Constant (ε∞)(ε∞) | 62.69 | - | DFT · OptB88vdW | ||
Electron Effective Mass(m*e) | 0.03667 | me | DFT · OptB88vdW · 27°C | ||
Hole Effective Mass(m*h) | 0.03667 | me | DFT · OptB88vdW · 27°C | ||
Thermoelectric Power Factor(PF)2 entries | 0.000174 | W/(m·K²) | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 0.0000207 | W/(m·K²) | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Seebeck Coefficient(S)2 entries | -186.3 | μV/K | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | -87.74 | μV/K | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.02970 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf) | -2.026 | eV/atom | DFT · OptB88vdW |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data