Ho₂Hf₂O₇ is a rare-earth hafnium oxide ceramic belonging to the pyrochlore family, engineered for extreme high-temperature thermal management applications. This material is primarily investigated for thermal barrier coatings and refractory applications in aerospace and advanced energy systems, where its hafnium base provides superior oxidation resistance and structural stability at temperatures exceeding conventional alumina-based systems. As a research compound, Ho₂Hf₂O₇ represents the broader class of rare-earth pyrochlores being developed to replace yttria-stabilized zirconia (YSZ) in next-generation gas turbines and hypersonic vehicle applications where enhanced thermal insulation and resistance to sintering degradation are critical.
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| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 0.3361 | lb/in³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg)2 entries | 3.203 | eV | DFT · OptB88vdW | ||
| ↳ | 4.835 | eV | DFT · TBmBJ | ||
High-Frequency Dielectric Constant (ε∞)(ε∞)2 entries | 4.526 | - | DFT · OptB88vdW | ||
| ↳ | 2.441 | - | DFT · TBmBJ | ||
Electron Effective Mass(m*e) | 0.6600 | me | DFT · OptB88vdW · 27°C | ||
Hole Effective Mass(m*h) | 1.380 | me | DFT · OptB88vdW · 27°C | ||
Magnetic Moment(μB) | 0.000 | µB | DFT · OptB88vdW | ||
Thermoelectric Power Factor(PF)2 entries | 0.000843 | W/(m·K²) | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 0.00200 | W/(m·K²) | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Seebeck Coefficient(S)2 entries | -152.5 | μV/K | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 381.3 | μV/K | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Spectroscopic Limited Maximum Efficiency (SLME)(SLME) | 0.000 | % | DFT · TBmBJ |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.00660 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf) | -3.826 | eV/atom | DFT · OptB88vdW |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data