Mercury sulfide (HgS), commonly known as cinnabar in its natural crystalline form, is an inorganic semiconductor compound that exists in two crystal phases with different electronic properties. Historically, HgS was the primary source of mercury metal extraction and remains significant in specialized optical and detector applications requiring narrow bandgap semiconductors, though its use is increasingly restricted due to mercury toxicity regulations. Modern interest in HgS focuses on narrow-bandgap IR detection, quantum dot synthesis for research, and specialized optoelectronic devices where its unique electronic structure offers advantages over conventional semiconductors, though engineers typically require careful handling protocols and regulatory compliance assessment before material selection.
Compliance & Regulations
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Bulk Modulus(K) | 7,798.7 | ksi | DFT · OptB88vdW | ||
Poisson's Ratio(ν) | 0.3900 | - | DFT · OptB88vdW | ||
Shear Modulus(G) | 2,111.7 | ksi | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 0.2619 | lb/in³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg)3 entries | 2.100 | eV | Measured | ||
| ↳ | 2.427 | eV | DFT · TBmBJ | ||
| ↳ | 1.399 | eV | DFT · OptB88vdW | ||
Dielectric Constant (Relative Permittivity)(εr)2 entries | 22.98 | - | DFT · OptB88vdW | ||
| ↳ | 12.33 | - | DFT · PBE | ||
High-Frequency Dielectric Constant (ε∞)(ε∞)2 entries | 8.947 | - | DFT · OptB88vdW | ||
| ↳ | 6.169 | - | DFT · TBmBJ | ||
Electronic Dielectric Tensor(ε∞) | Matrix (redacted) | - | DFT · PBE | ||
Total Dielectric Tensor(ε) | Matrix (redacted) | - | DFT · PBE | ||
Electron Effective Mass(m*e) | 0.7333 | me | DFT · OptB88vdW · 27°C | ||
Hole Effective Mass(m*h) | 2.753 | me | DFT · OptB88vdW · 27°C | ||
Magnetic Moment(μB) | 0.000 | µB | DFT · OptB88vdW | ||
Piezoelectric Modulus(eij) | 0.9069 | C/m² | DFT · OptB88vdW | ||
Thermoelectric Power Factor(PF)2 entries | 0.00100 | W/(m·K²) | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 0.00145 | W/(m·K²) | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Seebeck Coefficient(S)2 entries | -138.7 | μV/K | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 340.2 | μV/K | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Spectroscopic Limited Maximum Efficiency (SLME)(SLME) | 14.02 | % | DFT · TBmBJ |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.03240 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf)2 entries | 0.01627 | eV/atom | DFT · OptB88vdW | ||
| ↳ | -0.2762 | eV/atom | Measured |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data