Hafnium disilicide (HfSi2) is an intermetallic ceramic compound belonging to the refractory silicide family, characterized by exceptionally high melting points and oxidation resistance at elevated temperatures. It is primarily used in ultra-high-temperature structural applications and thermal protection systems, particularly in aerospace propulsion and hypersonic vehicle design where materials must withstand extreme thermal cycling and oxidative environments. HfSi2 offers advantages over competing refractory ceramics and metal alloys due to its combination of rigidity at temperature, relatively low density compared to other refractory silicides, and chemical stability in oxygen-rich atmospheres, making it valuable for applications where conventional nickel-based superalloys or alumina ceramics reach their performance limits.
Compliance & Regulations
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Bulk Modulus(K)3 entries | 131.9 | GPa | DFT | ||
| ↳ | 129.2 | GPa | DFT · OptB88vdW | ||
| ↳ | 131.9 | GPa | DFT · PBE | ||
Elastic Compliance Tensor(Sij) | Matrix (redacted) | 1/GPa | DFT · PBE | ||
Elastic Anisotropy(AU) | 0.3092 | - | DFT · PBE | ||
Elastic Stiffness Tensor(Cij) | Matrix (redacted) | Pa | DFT · PBE | ||
Poisson's Ratio(ν)2 entries | 0.2200 | - | DFT · OptB88vdW | ||
| ↳ | 0.2132 | - | DFT · PBE | ||
Shear Modulus(G)3 entries | 93.55 | GPa | DFT | ||
| ↳ | 91.37 | GPa | DFT · OptB88vdW | ||
| ↳ | 93.55 | GPa | DFT · PBE |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 7.796 | kg/m³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg)2 entries | 0.000 | eV | DFT · OptB88vdW | ||
| ↳ | 0.000 | eV | DFT · TBmBJ | ||
Magnetic Moment(μB) | 0.000 | µB | DFT · OptB88vdW | ||
Thermoelectric Power Factor(PF)2 entries | 0.00318 | W/(m·K²) | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 0.00334 | W/(m·K²) | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Seebeck Coefficient(S)2 entries | -38.31 | μV/K | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | -40.12 | μV/K | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.00670 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf) | -0.4843 | eV/atom | DFT · OptB88vdW |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data