HfO2

ceramic
· HfO2

Hafnium dioxide (HfO2) is a refractory ceramic oxide with high density and strong elastic properties, widely used in applications demanding thermal stability and electrical functionality. It serves as a high-κ dielectric in advanced semiconductor gate stacks, thermal barrier coatings in gas turbines and aerospace engines, and crucible/liner material in high-temperature metallurgical processes. Engineers select HfO2 over alternatives like SiO2 or Al2O3 when extreme temperature resistance, superior dielectric performance, or enhanced radiation stability are critical requirements.

semiconductor gate dielectricsthermal barrier coatingshigh-temperature cruciblesnuclear fuel claddingoptical coatingsrefractory applications

Compliance & Regulations

?Conflict Free?RoHS?REACH?TSCA?Prop 65
PropertyValueUnitConditionsSource
Bulk Modulus(K)3 entries
29,670.9
ksi
29,670.9
ksi
34,137.5
ksi
Elastic Compliance Tensor(Sij)
Matrix (redacted)
1/GPa
Elastic Anisotropy(AU)
0.3858
-
Elastic Stiffness Tensor(Cij)
Matrix (redacted)
ksi
Poisson's Ratio(ν)2 entries
0.2924
-
0.2800
-
Shear Modulus(G)3 entries
14,295.6
ksi
14,295.6
ksi
17,607.6
ksi
N entriesMultiple entries per property — large groups are collapsed; click a summary row to expand. Use filters above to narrow by form / heat treatment / basis.
Verified Unverified Low confidence (<80%) Link to source
PropertyValueUnitConditionsSource
Density(ρ)
0.3795
lb/in³
Verified Unverified Low confidence (<80%) Link to source
PropertyValueUnitConditionsSource
Band Gap(Eg)2 entries
5.550
eV
4.315
eV
Dielectric Constant (Relative Permittivity)(εr)3 entries
18.75
-
35.32
-
16.97
range 4.659–29.27median of 2 measurements
-
Electronic Dielectric Tensor(ε∞)
Matrix (redacted)
-
Total Dielectric Tensor(ε)
Matrix (redacted)
-
Magnetic Moment(μB)
0.000
µB
Piezoelectric Modulus(eij)2 entries
1.219
C/m²
0.000
C/m²
Piezoelectric Stress Tensor(eij)
Matrix (redacted)
C/m²
Seebeck Coefficient(S)
-285.6
µV/K
N entriesMultiple entries per property — large groups are collapsed; click a summary row to expand. Use filters above to narrow by form / heat treatment / basis.
Verified Unverified Low confidence (<80%) Link to source
PropertyValueUnitConditionsSource
Energy Above Hull(ΔEhull)
0.01180
eV/atom
Formation Energy(ΔHf)2 entries
-3.861
eV/atom
-3.798
eV/atom
N entriesMultiple entries per property — large groups are collapsed; click a summary row to expand. Use filters above to narrow by form / heat treatment / basis.
Verified Unverified Low confidence (<80%) Link to source

Regulatory Screening

Environmental

RoHS, REACH, and Prop 65 statuses are validated against official substance lists (ECHA SVHC Candidate List, OEHHA Prop 65, RoHS Annex II). Other regulations are estimated from composition and material classification. All screening is a starting point for due diligence — always verify with your supplier before making compliance decisions.
HfO2 — Properties & Data | MatWorld