Ag₄Hg₄S₄I₄ is a mixed-halide semiconductor compound combining silver, mercury, sulfur, and iodine in a 1:1:1:1 stoichiometry. This is a research-phase material within the family of complex chalcohalide semiconductors, studied primarily for optoelectronic and photovoltaic applications where its unique bandgap and mixed-anion coordination offer tunable electronic properties. The material remains largely experimental; its practical adoption depends on overcoming challenges common to mercury-containing semiconductors, including toxicity concerns, environmental stability, and scalable synthesis, though it represents a promising direction for next-generation solid-state light emitters and detectors.
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| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Bulk Modulus(K) | 3,727.5 | ksi | — | ||
Shear Modulus(G) | 1,053 | ksi | — |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg) | 1.233 | eV | — |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Formation Energy(ΔHf) | -0.1810 | eV/atom | — |