PbSe (lead selenide) is a narrow-bandgap IV–VI semiconductor compound with a rock-salt crystal structure, commonly produced as polycrystalline ingots or epitaxial films. It is the primary material for mid-infrared (3–5 μm) photodetectors and thermal imaging sensors operating at cryogenic to room temperature, and serves as a host lattice for quantum dots in optoelectronic research. Engineers select PbSe over alternatives like InSb or HgCdTe when cost and ease of fabrication are priorities, though it requires careful temperature management and surface passivation to control dark current and leakage; recent interest focuses on nanocrystal forms for tunable bandgap and solution-processable device architectures.
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| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Bulk Modulus(K)2 entries | 47.14 | GPa | DFT | ||
| ↳ | 50.29 | GPa | DFT · OptB88vdW | ||
Poisson's Ratio(ν) | 0.2600 | - | DFT · OptB88vdW | ||
Shear Modulus(G)2 entries | 27.41 | GPa | DFT | ||
| ↳ | 33.33 | GPa | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Density(ρ) | 8.009 | kg/m³ | DFT · OptB88vdW |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg)3 entries | 0.1700 | eV | Measured | ||
| ↳ | 0.5130 | eV | DFT · OptB88vdW | ||
| ↳ | 0.9620 | eV | DFT · TBmBJ | ||
Dielectric Constant (Relative Permittivity)(εr)2 entries | 173.7 | - | DFT · OptB88vdW | ||
| ↳ | 82.07 range 21.72–142.4median of 2 measurements | - | DFT · PBEsol | ||
High-Frequency Dielectric Constant (ε∞)(ε∞)2 entries | 20.44 | - | DFT · OptB88vdW | ||
| ↳ | 14.03 | - | DFT · TBmBJ | ||
Electron Effective Mass(m*e) | 0.1400 | me | DFT · OptB88vdW · 27°C | ||
Hole Effective Mass(m*h) | 0.1500 | me | DFT · OptB88vdW · 27°C | ||
Magnetic Moment(μB) | 0.000 | µB | DFT · OptB88vdW | ||
Piezoelectric Modulus(eij) | 0.000 | C/m² | DFT · OptB88vdW | ||
Thermoelectric Power Factor(PF)2 entries | 0.00166 | W/(m·K²) | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 0.00275 | W/(m·K²) | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Seebeck Coefficient(S)2 entries | -112.6 | μV/K | DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C | ||
| ↳ | 153.4 | μV/K | DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C | ||
Spectroscopic Limited Maximum Efficiency (SLME)(SLME) | 31.61 | % | DFT · TBmBJ |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Energy Above Hull(ΔEhull) | 0.000 | eV/atom | DFT · OptB88vdW | ||
Formation Energy(ΔHf)2 entries | -0.5955 | eV/atom | DFT · OptB88vdW | ||
| ↳ | -0.5182 | eV/atom | Measured |
Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data