PbO2 — Properties & Data | MatWorld

PbO2

Name: PbO2
Brand: MatWorld

semiconductor

· PbO2

Lead dioxide (PbO2) is a dense ceramic semiconductor compound widely used as the positive electrode material in lead-acid batteries, where its high electrochemical stability and conductivity enable reliable charge-discharge cycling. In industrial applications, PbO2 is valued for electrochemical synthesis and water treatment processes, particularly in electrodes for organic pollutant oxidation and electrorefining operations, where its strong oxidizing potential and corrosion resistance in acidic environments outperform many alternatives. The material's brittleness and toxicity concerns limit its use to enclosed electrochemical systems where environmental containment is feasible.

lead-acid battery electrodeselectrochemical water treatmentelectrorefining and metal recoveryorganic waste oxidationindustrial electrosynthesiscorrosion-resistant anodes

Compliance & Regulations

?EAR?Conflict Free?RoHS?REACH?TSCA?Prop 65

Units:

si imperial

Property	Value	Unit	Conditions
Bulk Modulus(K)	124.6	GPa	DFT · OptB88vdW
Poisson's Ratio(ν)	0.3300	-	DFT · OptB88vdW
Shear Modulus(G)	55.49	GPa	DFT · OptB88vdW

Verified Unverified Low confidence (<80%) Link to source

Property	Value	Unit	Conditions	Source
Density(ρ)	9.021	kg/m³	DFT · OptB88vdW

Verified Unverified Low confidence (<80%) Link to source

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Method

Carrier

Property	Value	Unit	Conditions
Band Gap(Eg)3 entries	1.450	eV	Measured
↳	0.02500	eV	DFT · OptB88vdW
↳	0.1140	eV	DFT · TBmBJ
High-Frequency Dielectric Constant (ε∞)(ε∞)2 entries	11.98	-	DFT · OptB88vdW
↳	8.782	-	DFT · TBmBJ
Magnetic Moment(μB)	0.000	µB	DFT · OptB88vdW
Thermoelectric Power Factor(PF)2 entries	0.000717	W/(m·K²)	DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C
↳	0.000420	W/(m·K²)	DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C
Seebeck Coefficient(S)2 entries	-80.02	μV/K	DFT · OptB88vdW · n-type · 1e20 cm⁻³ · 327°C
↳	-72.49	μV/K	DFT · OptB88vdW · p-type · 1e20 cm⁻³ · 327°C
Spectroscopic Limited Maximum Efficiency (SLME)(SLME)	5.840	%	DFT · TBmBJ

N entriesMultiple entries per property — large groups are collapsed; click a summary row to expand. Use filters above to narrow by form, heat treatment, basis, or test environment.

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Method

Property	Value	Unit	Conditions
Energy Above Hull(ΔEhull)	0.00360	eV/atom	DFT · OptB88vdW
Formation Energy(ΔHf)2 entries	-0.9431	eV/atom	DFT · OptB88vdW
↳	-0.9483	eV/atom	Measured

N entriesMultiple entries per property — large groups are collapsed; click a summary row to expand. Use filters above to narrow by form, heat treatment, basis, or test environment.

Verified Unverified Low confidence (<80%) Link to source

Reference data from cited sources. Not verified or certified by MatWorld Inc. Verify against the source before use in design. Terms: engineering data

Regulatory Screening

Environmental

Export Control

RoHS, REACH, and Prop 65 statuses are validated against official substance lists (ECHA SVHC Candidate List, OEHHA Prop 65, RoHS Annex II). Other regulations are estimated from composition and material classification. All screening is a starting point for due diligence — always verify with your supplier before making compliance decisions.

PbO2

Mechanical Properties

Physical Properties

Electrical Properties

Other Properties

Regulatory Screening

Environmental

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