Na4Ni4O6 is a mixed-valence sodium-nickel oxide ceramic compound belonging to the layered oxide family, characterized by its semiconductor properties and complex crystal structure. This material is primarily of research interest in energy storage and electrochemistry applications, particularly as a potential cathode material for sodium-ion batteries and electrochemical devices seeking alternatives to lithium-based systems. Its appeal lies in the abundance of sodium and nickel compared to lithium, making it relevant for cost-sensitive, large-scale energy storage where electrochemical activity and structural stability during ion insertion/extraction cycles are critical performance factors.
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| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Bulk Modulus(K) | 50.51 | GPa | — | ||
Shear Modulus(G) | 18.59 | GPa | — |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg) | 0.01060 | eV | — |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Formation Energy(ΔHf) | -1.060 | eV/atom | — |