Bismuth oxide (Bi₂O₃) is an n-type semiconductor ceramic compound that exists in multiple crystal phases, with the cubic δ-phase being most relevant for electronic applications. It is primarily used in optoelectronic devices, gas sensors, photocatalysts, and emerging applications in solid oxide fuel cells (SOFCs), where its ionic conductivity and optical properties are leveraged. Bi₂O₃ is notable for its low bandgap energy and high dielectric constant compared to conventional semiconductors, making it attractive for applications requiring visible-light responsiveness or high-temperature ionic transport, though it remains less mature than established semiconductor platforms.
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| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Bulk Modulus(K) | 112.4 range 99.41–125.5median of 2 measurements | GPa | — | ||
Shear Modulus(G) | 30.42 range 19.87–40.97median of 2 measurements | GPa | — |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Band Gap(Eg) | 0.8259 range 0.1977–1.454median of 2 measurements | eV | — |
| Property | Value | Unit | Conditions | Source | |
|---|---|---|---|---|---|
Formation Energy(ΔHf) | -1.248 range -1.313–-1.184median of 2 measurements | eV/atom | — |